Hello,
Most of the series (including NBarSeries) have an UseXValues property - you have to set this to "true" and then fill the X values in the XValues data series. You can take a look at the following examples:
All Examples > Chart Gallery > Bar > Date Time Bars
All Examples > Chart Gallery > Bar > XYZ Scatter Stack
All Examples > Chart Gallery > Bar > XYZ Scatter Cluster
All Examples > Chart Gallery > Line > XY Scatter Line